HCID 53740121, compound → HCID 13037713, compound

HRID 1088499Notes

Reaction equation

HRID 1088499 reaction equation
[CH3:1][C:2](=[N:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:3]1[CH:8]=[CH:7][C:6]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])=[CH:5][CH:4]=1>[Pd].C(O)C>[CH3:1][CH:2]([NH:17][C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)[C:3]1[CH:8]=[CH:7][C:6]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])=[CH:5][CH:4]=1

Participants

4

Reactant 1

HCID 53740121HCID 53740121, compound

Product 1

HCID 13037713HCID 13037713, compoundYield 82.1%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

N-(α-methyl-p-octyl benzylidene) aniline (49 g), prepared by the procedure described in Example IA was hydrogenated using 5% Pd/C as the catalyst and 95% ethanol as the solvent. N-(α-methyl-p-octyl-benzyl)aniline (II) (40.5 g) was obtained by fractional distillation. The desired product II had a boiling point of 173° to 178° C. at 0.025 millimeter.

Sources & evidence

ORD record
ord-1fb98bee9ec64610a6bf4013c8224458
Source dataset
uspto-grants-1990_10
Patent number
US04962234

Reaction notes

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