HCID 22163145, compound → HCID 22163150, compound

HRID 1088510Notes

Reaction equation

HRID 1088510 reaction equation
[CH3:1][C:2](=[N:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([C:16]([O:18][CH2:19][CH3:20])=[O:17])[CH:11]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>[Pd].C(O)C>[CH3:1][CH:2]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([C:16]([O:18][CH2:19][CH3:20])=[O:17])[CH:11]=1)[C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][CH:8]=1

Participants

4

Reactant 1

HCID 22163145HCID 22163145, compound

Product 1

HCID 22163150HCID 22163150, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

N-(α-methyl benzylidene)m-carbethoxyaniline (27 g) prepared by the procedure described in example VIIA was hydrogenated using 5% Pd/C as the catalyst and 95% ethanol as the solvent. N-(α-methyl benzyl m-carbethoxy aniline (XIV) was obtained by fractional distillation. XIV had a boiling point of 156° C. at 0.1 millimeter.

Sources & evidence

ORD record
ord-4246d3f98b8f4977af70228eeef40f60
Source dataset
uspto-grants-1990_10
Patent number
US04962234

Reaction notes

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