HCID 22163142, compound → HCID 22163147, compound

HRID 1088512Notes

Reaction equation

HRID 1088512 reaction equation
[CH3:1][C:2](=[N:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[C:16]([O:18][CH2:19][CH3:20])=[O:17])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>[Pd].C(O)C>[CH3:1][CH:2]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[C:16]([O:18][CH2:19][CH3:20])=[O:17])[C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][CH:8]=1

Participants

4

Reactant 1

HCID 22163142HCID 22163142, compound

Product 1

HCID 22163147HCID 22163147, compoundYield 91.6%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

N-(α-methyl benzylidene)-o-carbethoxyaniline (13 g) prepared by the procedure described in example XXVA was hydrogenated using 5% Pd/C as the catalyst and 95% ethanol as the solvent. N-(α-methyl benzyl)-o-carbethoxyaniline (XVI) (12 g) was obtained by fractional distillation. XVI had a boiling point of 168° C. at 1.4 millimeter.

Sources & evidence

ORD record
ord-41be958c702f455b8cd074853f3045cc
Source dataset
uspto-grants-1990_10
Patent number
US04962234

Reaction notes

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