p-acetyl-N-(alpha-methyl benzylidene) aniline → p-Acetyl-N-(alpha-methyl benzyl) aniline
Reaction equation
[C:1]([C:4]1[CH:18]=[CH:17][C:7]([N:8]=[C:9]([CH3:16])[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)(=[O:3])[CH3:2]>[Pd].C(O)C>[C:1]([C:4]1[CH:18]=[CH:17][C:7]([NH:8][CH:9]([CH3:16])[C:10]2[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=2)=[CH:6][CH:5]=1)(=[O:3])[CH3:2]Participants
4
Reactant 1
Product 1
Reagents, catalysts & solvents 2
Procedure
p-Acetyl-N-(α-methylbenzylidene) aniline (XXIII) (30 g) prepared by the procedure described in Example XXIXA was hydrogenated using 5% Pd/C as the catalyst and 95% ethanol as the solvent. p-Acetyl-N-(α-methyl benzyl) aniline (XXIV) was obtained by fractional distillation. XXIV had a boiling point of 165° C. at 0.1 millimeter.
Sources & evidence
- ORD record
- ord-3a8dfda1578a4d7d8b425c809dde6ebd
- Source dataset
- uspto-grants-1990_10
- Patent number
- US04962234
Reaction notes
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