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HRID1089089

反应详情

EQUATION

反应方程式

HRID 1089089 的结构方程式

REACTANTS

反应物

2
结构：CC(=O)c1cccnc1
HCID9589

3-Acetylpyridine

C7H7NO

结构：CC(=O)c1ccncc1
HCID14282

4-Acetylpyridine

C7H7NO

PRODUCTS

生成物

1
结构：C[C@@H](O)c1ccncc1
HCID11804747

(R)-1-(pyridin-4-yl)ethanol

C7H9NO

PROCEDURE

实验过程

Example 1 was repeated except that 3-acetylpyridine used in Example 1 was replaced by 4-acetylpyridine to obtain (R)-1-(4-pyridyl)ethanol. [a]D25 =+32.4° (c=1.0, EtOH). Its optical purity was 99% ee or higher according to a high-speed liquid chromatography using an optical resolution column (CHIRAL CEL OB made by Daicel K. K.).