Benzyl Alcohol → HCID 13668648, compound

HRID 1089653Notes

Reaction equation

HRID 1089653 reaction equation
[CH2:1]([OH:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:9]([O:11][CH2:12][CH:13]([CH3:15])[CH3:14])=[CH2:10].C(=O)([O-])[O-].[Na+].[Na+]>Cl>[CH2:1]([O:8][CH:9]([O:11][CH2:12][CH:13]([CH3:15])[CH3:14])[CH3:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 244Benzyl AlcoholHCID 7992Vinyl isobutyl etherHCID 10340Sodium Carbonate

Product 1

HCID 13668648HCID 13668648, compound

Reagents, catalysts & solvents 1

HCID 313Hydrochloric AcidCatalyst

Conditions

Temperature
40 °C

Procedure

A 250 ml. round-bottom flask equipped with a magnetic stirrer, condensor, mantle, and addition funnel was charged with 52.5 g. of benzyl alcohol and 4 drops of 36% hydrochloric acid. The mixture was heated to 40° C. and 50 g. of isobutyl vinyl ether was added dropwise, over a one-half hour period. GLC analysis showed the reaction to be complete at this point. Saturated sodium carbonate solution was added to quench (10 ml.) and the organic phase was dried over sodium sulfate prior to distillation on a concentric tube column:

Workup

  1. customround-bottom flask equipped with a magnetic stirrer
  2. additioncondensor, mantle, and addition funnel
  3. additionwas charged with 52.5 g
  4. customthe reaction
  5. customto quench (10 ml.)
  6. dry with materialthe organic phase was dried over sodium sulfate
  7. distillationto distillation on a concentric tube column

Sources & evidence

ORD record
ord-0241e3b3fb7c46cebc1f1c0091b440c6
Source dataset
uspto-grants-1992_01
Patent number
US05079023

Reaction notes

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