Chlorine → HCID 19779379, compound

HRID 1089686Notes

Reaction equation

HRID 1089686 reaction equation
[Cl:1]Cl.[NH2:3][C:4]1[CH:9]=[CH:8][C:7]([C:10]([F:13])([F:12])[F:11])=[CH:6][C:5]=1[C:14]#[N:15]>C(Cl)(Cl)(Cl)Cl>[NH2:3][C:4]1[C:5]([C:14]#[N:15])=[CH:6][C:7]([C:10]([F:11])([F:12])[F:13])=[CH:8][C:9]=1[Cl:1]

Participants

4

Reactant 2

HCID 24526ChlorineHCID 126273614-Amino-3-cyanobenzotrifluoride

Product 1

HCID 19779379HCID 19779379, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

Chlorine gas was passed through a stirred solution of 4-amino-3-cyanotrifluoromethyl-benzene (5 g) in carbon tetrachloride (75 ml) until the absence of starting material was confirmed by gas liquid chromatography. Flow of the gas was then stopped and evaporation of the solvent under reduced pressure gave 4-amino-3-chloro-5-cyano-trifluoromethyl benzene as an orange solid (5.5 g).

Workup

  1. customevaporation of the solvent under reduced pressure

Sources & evidence

ORD record
ord-3b7028b28ce64a4596a8004e65ad5f09
Source dataset
uspto-grants-1992_01
Patent number
US05079251

Reaction notes

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