Ethanol → HCID 15023448, compound

HRID 1089751Notes

Reaction equation

HRID 1089751 reaction equation
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:6]3[C:10]=1[N:9]([CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:8](=S)[C:7]=3[CH:19]=[CH:20][CH:21]=2.[N:22]1([CH2:27][CH2:28][CH2:29][NH2:30])[CH:26]=[CH:25][N:24]=[CH:23]1.C(O)C>CN(C)C=O>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:6]3[C:10]=1[N:9]([CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:8](=[N:30][CH2:29][CH2:28][CH2:27][N:22]1[CH:26]=[CH:25][N:24]=[CH:23]1)[C:7]=3[CH:19]=[CH:20][CH:21]=2

Participants

5

Reactant 3

HCID 702EthanolHCID 787361H-Imidazole-1-propanamineHCID 15023425HCID 15023425, compound

Product 1

HCID 15023448HCID 15023448, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

A mixture of 2.9 g of (8-methyl-1-(phenylmethyl)benz[cd]indole-2(1H)-thione (Cq), 1.4 g of 1H-imidazole-1-propanamine, 250 ml of ethanol, 50 ml of dimethylformamide, and 3.5 g of mercuric acetate is reacted as described in Example 3, giving I.6 g of the desired product, mp 107°-109° C.

Workup

  1. customis reacted
  2. customgiving I

Sources & evidence

ORD record
ord-49a77f9e4b7445dcb7876254d5f4f117
Source dataset
uspto-grants-1992_01
Patent number
US05079247

Reaction notes

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