Hydrochloric Acid → HCID 178426313, compound

Participants

Reaction Conditions

Reaction Steps

To 100 ml of HMPA were added 10.0 g (54.3 mmoles) of 3-cyano-4-imino-9-methyl-4H-pyrido[1,2-a]-pyrimidine and 3.53 g (54.3 mmoles) of sodium azide, and the reaction was carried out with stirring at 70° C. for 3 hours. After cooling, the reaction mixture was neutralized with diluted hydrochloric acid, and the crystals precipitated were collected by filtration to obtain 9.8 9 of light-brown power of 3-(3-methyl-2-pyridyl)amino-2-(1H-tetrazol-5-yl)-2-propenonitrile. Yield: 79%.

Provenance & Evidence