Carbon Dioxide → HCID 20535609, compound

HRID 1105606Notes

Reaction equation

HRID 1105606 reaction equation
[Cl:1][C:2]([O:4][CH2:5][CH3:6])=O.[CH2:7]([NH:10]C=O)[CH:8]=[CH2:9].C(=O)=O>>[ClH:1].[CH2:5]([O:4][CH:2]=[N:10][CH2:7][CH:8]=[CH2:9])[CH3:6]

Participants

4

Reactant 3

HCID 280Carbon DioxideHCID 10928Ethyl chloroformateHCID 254129n-allylformamide

Product 1

HCID 20535609HCID 20535609, compound

Conditions

Temperature
45 °C

Procedure

Ethyl chloroformate (2.66 g., 24.47 mmole) is added by syringe to N-allylformamide (2.08 g., 24.47 mmole) in a dry flask under N2. The resulting mixture is then stirred at 25° C., for 2 hours during which time CO2 is rapidly evolved. The reaction mixture is then heated to 45° C. until no further evolution of gas is evident (2 hours). The viscous product is then cooled and held at a vacuum of 0.2 mm for 2 hours to remove all volatiles.

Workup

  1. custom(2 hours)
  2. temperatureThe viscous product is then cooled
  3. customto remove all volatiles

Sources & evidence

ORD record
ord-5dd139559b0e41f99174d046c6af897e
Source dataset
uspto-grants-1982_01
Patent number
US04309438

Reaction notes

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