HCID 12452036, compound → HCID 20554163, compound

HRID 1106015Notes

Reaction equation

HRID 1106015 reaction equation
[F:1][C:2]([N+:21]([O-:23])=[O:22])([N+:18]([O-:20])=[O:19])[CH2:3][N:4]([CH2:9][C:10]([N+:15]([O-:17])=[O:16])([N+:12]([O-:14])=[O:13])[F:11])[C:5]([NH:7][NH2:8])=[O:6].[F:24][C:25]([N+:31]([O-:33])=[O:32])([N+:28]([O-:30])=[O:29])[C:26]#[N:27]>>[F:1][C:2]([N+:21]([O-:23])=[O:22])([N+:18]([O-:20])=[O:19])[CH2:3][N:4]([CH2:9][C:10]([N+:15]([O-:17])=[O:16])([N+:12]([O-:14])=[O:13])[F:11])[C:5]([NH:7][N:8]=[N:27][CH2:26][C:25]([F:24])([N+:31]([O-:33])=[O:32])[N+:28]([O-:30])=[O:29])=[O:6]

Participants

3

Reactant 2

HCID 12452036HCID 12452036, compoundHCID 13015165HCID 13015165, compound

Product 1

HCID 20554163HCID 20554163, compound

Procedure

The initial derivatives prepared from I can also be useful intermediates for the synthesis of other explosive materials. For example [N,N-bis(2-fluoro-2,2-dinitroethyl)carbamyl]hydrazine (VI) was added to fluorodinitroacetonitrile to give 1-[N,N-bis(2-fluoro-2,2-dinitroethyl)carbamyl]-2-(2-fluoro-2,2-dinitroethylimino)hydrazine (IX). Compound IX was hydrolyzed to give 1-[N,N-bis(2-fluoro-2,2-dinitroethyl)carbamyl]-2-fluorodinitroacetyl hydrazine (X) and cyclized with trifluoroacetic anhydride to yield trifluoroacetyl-3-[bis(2-fluoro-2,2-dinitroethyl)amino]-5-fluorodinitromethyl-1,2,4-triazole (XI).

Workup

  1. customThe initial derivatives prepared from I can also be useful intermediates
  2. customfor the synthesis of other explosive materials

Sources & evidence

ORD record
ord-6ab3ba06729b400dafde75715527d1f9
Source dataset
uspto-grants-1982_01
Patent number
US04311649

Reaction notes

Loading…