m-Chloroperbenzoic acid → HCID 20553732, compound

HRID 1106236Notes

Reaction equation

HRID 1106236 reaction equation
[Br:1][C:2]1[S:3][CH:4]=[C:5]([CH2:7][C:8]2[CH:13]=[CH:12][C:11]([S:14][C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)=[CH:10][CH:9]=2)[N:6]=1.ClC1C=CC=C(C(OO)=[O:29])C=1>C(Cl)(Cl)Cl>[Br:1][C:2]1[S:3][CH:4]=[C:5]([CH2:7][C:8]2[CH:9]=[CH:10][C:11]([S:14]([C:15]3[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=3)=[O:29])=[CH:12][CH:13]=2)[N:6]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 20553733HCID 20553733, compound

Product 1

HCID 20553732HCID 20553732, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The starting 2-bromo-4-(4-phenylsulfinylbenzyl)thiazole was prepared by mild oxydation of 2-bromo-4-(4-phenylthiobenzyl)thiazole, M.P. 82° C., by the means of meta-chloroperbenzoic acid in chloroform.

Sources & evidence

ORD record
ord-c2708b3270da4cf7af7514a3c7a7ba5a
Source dataset
uspto-grants-1982_01
Patent number
US04312869

Reaction notes

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