m-Chloroperbenzoic acid → HCID 20553734, compound

HRID 1106238Notes

Reaction equation

HRID 1106238 reaction equation
[C:1]1([S:7][C:8]2[CH:13]=[CH:12][C:11]([CH2:14][C:15]([CH2:17][Cl:18])=[O:16])=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.ClC1C=CC=C(C(OO)=[O:27])C=1>C(Cl)(Cl)Cl>[C:1]1([S:7]([C:8]2[CH:9]=[CH:10][C:11]([CH2:14][C:15]([CH2:17][Cl:18])=[O:16])=[CH:12][CH:13]=2)=[O:27])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 53845099HCID 53845099, compound

Product 1

HCID 20553734HCID 20553734, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The starting 1-(4-phenylsulfinylphenyl)-3-chloro acetone was prepared by mild oxydation in chloroform, of 1-(4-phenylthiophenyl)-3-chloro acetone with meta-chloro perbenzoic acid.

Sources & evidence

ORD record
ord-4ab83f30109949b988f13380e379e5b7
Source dataset
uspto-grants-1982_01
Patent number
US04312869

Reaction notes

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