n-Butyl cyclopentadiene → HCID 178506708、化合物

HRID 1107020ノート

反応式

HRID 1107020 の反応式
C([Li:5])CCC.[CH2:6]([C:10]1[CH2:14][CH:13]=[CH:12][CH:11]=1)[CH2:7][CH2:8][CH3:9]>CCCCCC.C1COCC1>[CH2:6]([C:10]1([Li:5])[CH:14]=[CH:13][CH:12]=[CH:11]1)[CH2:7][CH2:8][CH3:9]

参加物

5

反応物 2

HCID 102598n-Butyl cyclopentadieneHCID 178418339Butyllithium

生成物 1

HCID 178506708HCID 178506708、化合物

試薬・触媒・溶媒 2

HCID 8028Tetrahydrofuran溶媒HCID 8058Hexane溶媒

実験手順

Being cooled in an ice-water bath, a solution 36.1 ml of butyl lithium(0.090 mol) in 2.5M hexane was slowly dripped to a solution of 11.0 g(0.090 mol) of butyl-cyclopentadiene in 100 ml THF with stirring. After the dripping was finished, the resultant mixture was continuously stirred for 1 hour, a white muddy solution of butyl-cyclopentadienyl lithium was then obtained.

後処理

  1. temperatureBeing cooled in an ice-water bath

出典と根拠

ORDレコード
ord-d0d2c6011de4479eaf3e42635ed157dc
出典データセット
uspto-grants-2000_05
特許番号
US06057467

反応ノート

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