HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → HCID 9957112, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 3-Piperidinol, 1-methyl- | HCID 98016 | — |
| Reactant | Diethyl azodicarboxylate | HCID 5462977 | — |
| Reactant | 2-(4-Methoxyphenyl)-3-(4-Hydroxybenzoyl)-6-Methoxybenzo[b]thiophene | HCID 9865197 | — |
| Product | HCID 9957112 | HCID 9957112 | 21% |
Reaction Steps
6-Methoxy-2-(4-methoxyphenyl)-3-(4-hydroxybenzoyl)benzo[b]thiophene (1.17 g, 3.00 mmol), 1-methyl-3-hydroxypiperidine (691 mg, 6.00 mmol), triphenylphosphine (1.57 g, 6.00 mmol), and DEAD (6.0 mmol) were converted to product by the procedure of Example 11 to give 307 mg of the title compound. Yield: 21%. MS(FD) 487(M+). IR (CHCl3) ν max 3010, 2947, 2840, 2795, 1646, 1599, 1476, 1254, 1167.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06060488 |
| Source dataset | uspto-grants-2000_05 |
| ORD ID | ord-938f27edbbee4eb79a9bf93ebe477c6e |
| Source note | uspto-grants-2000_05 |