Trimethoxysilane → HCID 54568787, compound

HRID 1108855Notes

Reaction equation

HRID 1108855 reaction equation
[CH:1]([O:4][CH2:5][CH2:6][O:7][CH:8]=[CH2:9])=[CH:2][CH3:3].[SiH:10]([O:15][CH3:16])([O:13][CH3:14])[O:11][CH3:12]>C1(C)C=CC=CC=1>[CH:1]([O:4][CH2:5][CH2:6][O:7][CH2:8][CH2:9][Si:10]([O:15][CH3:16])([O:13][CH3:14])[O:11][CH3:12])=[CH:2][CH3:3]

Participants

4

Reactant 2

HCID 17215TrimethoxysilaneHCID 54551299HCID 54551299, compound

Product 1

HCID 54568787HCID 54568787, compoundYield 36%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
85 °C

Procedure

Into a 100 mL round bottom flask were added 9.17 grams (0.07 mol) of 1-(1-propenoxy)-2-vinyloxyethane, 3 mg of (PPh3)3RuCl2, 11.3 grams of (MeO)3SiH (0.09 mol), and 15 ml of dried toluene. The resulting purple solution was refluxed at 85° C. for 12 hours. Fractional vacuum distillation yielded 1-(1-propenoxy)-2(2-trimethoxysilylethoxy)ethane (V) in 36% yield as a colorless liquid, b.p. 70° C./0.15 mm Hg.

Workup

  1. distillationFractional vacuum distillation

Sources & evidence

ORD record
ord-3b019b93be824e5d86e1fcbe26ab4875
Source dataset
uspto-grants-2000_05
Patent number
US06069259

Reaction notes

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