HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 178444582, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | 4-(Trifluoromethyl)benzaldehyde | HCID 67996 | — |
| Reactant | 2-Pentyl-1,3-propanediol | HCID 117509 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 178444582 | HCID 178444582 | — |
Reaction Steps
An equimolar mixture of p-trifluoromethylbenzaldehyde and 2-pentylpropane-1,3-diol in toluene is boiled on a water separator with catalysis by p-toluenesulfonic acid. When the water separation is complete and after conventional work-up, p-(trans-5-n-pentyl-1,3-dioxan-2-yl)-trifluorotoluene, m.p. 44.3°, Δε=+12.9, is obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05318721 |
| Source dataset | uspto-grants-1994_06 |
| ORD ID | ord-101fa1da6c0f46b0ae3d6252e2448807 |
| Source note | uspto-grants-1994_06 |