HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexane → HCID 11831478, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexane | HCID 8058 | — |
| Reactant | HCID 86747931 | HCID 86747931 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Catalyst | Benzyltriphenylphosphonium chloride | HCID 70671 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 11831478 | HCID 11831478 | — |
Reaction Steps
Using the procedure of Preparation H1, 2.37 g of triphenyl benzyl phosphonium chloride (Aldrich), 1.0 g of methyl 3-carbonylbenzoate and 2.44 ml of 2.5M solution of n-butyl lithium in hexane in 50 ml (total) of tetrahydrofuran gave 208 mg of the titled product, m.p. 108°-109° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05322847 |
| Source dataset | uspto-grants-1994_06 |
| ORD ID | ord-a246fef99fae4428b3abccfdd87dece3 |
| Source note | uspto-grants-1994_06 |