HRID1110697

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID192414

未命名化合物

结构：CC(C)[C@H](NC(=O)CNC(=O)[C@H](Cc1ccccc1)NC(=O)CNC(=O)OC(C)(C)C)C(=O)NCC(=O)N[C@@H](C)C(=O)NCC(=O)N[C@H](C(=O)N1CCC[C@H]1C(=O)OCc1ccccc1)C(C)C

HCID131715253

未命名化合物

PRODUCTS

生成物

结构：CC(C)[C@H](NC(=O)CNC(=O)[C@H](Cc1ccccc1)NC(=O)CNC(=O)OC(C)(C)C)C(=O)NCC(=O)N[C@@H](C)C(=O)NCC(=O)N[C@H](C(=O)N1CCC[C@H]1C(=O)O)C(C)C

HCID131715256

未命名化合物

PROCEDURE

实验过程

The above peptide XV was hydrogenated as described for the preparation VIII to obtain the product in quantitative yield. Rf3 0.22. Anal. calcd. for C40H61N9O12:C 55.66, H 7.12, N 14.60%. Found: C 55.86, H 7.23, N 14.14%.

WORKUP

后处理

customto obtain the product in quantitative yield

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-30dc1d449a2247ffb4e2b521972541e5
来源数据集: uspto-grants-1990_12
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04976734
来源说明: uspto-grants-1990_12

反应 SMILES

[NH:1]([C:62]([O:64][C:65]([CH3:68])([CH3:67])[CH3:66])=[O:63])[CH2:2][C:3]([NH:5][C@H:6]([C:14]([NH:16][CH2:17][C:18]([NH:20][C@H:21]([C:25]([NH:27][CH2:28][C:29]([NH:31][C@H:32]([C:34]([NH:36][CH2:37][C:38]([NH:40][C@H:41]([C:45]([N:47]1[CH2:61][CH2:60][CH2:59][C@H:48]1[C:49]([O:51]CC1C=CC=CC=1)=[O:50])=[O:46])[CH:42]([CH3:44])[CH3:43])=[O:39])=[O:35])[CH3:33])=[O:30])=[O:26])[CH:22]([CH3:24])[CH3:23])=[O:19])=[O:15])[CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[O:4].N(C(OC(C)(C)C)=O)[C@H](C(NCC(O)=O)=O)C>>[NH:1]([C:62]([O:64][C:65]([CH3:68])([CH3:67])[CH3:66])=[O:63])[CH2:2][C:3]([NH:5][C@H:6]([C:14]([NH:16][CH2:17][C:18]([NH:20][C@H:21]([C:25]([NH:27][CH2:28][C:29]([NH:31][C@H:32]([C:34]([NH:36][CH2:37][C:38]([NH:40][C@H:41]([C:45]([N:47]1[CH2:61][CH2:60][CH2:59][C@H:48]1[C:49]([OH:51])=[O:50])=[O:46])[CH:42]([CH3:44])[CH3:43])=[O:39])=[O:35])[CH3:33])=[O:30])=[O:26])[CH:22]([CH3:24])[CH3:23])=[O:19])=[O:15])[CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[O:4]