1,2-Dichloro-4-nitrobenzene → HCID 22765592, compound

HRID 1111855Notes

Reaction equation

HRID 1111855 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7](Cl)=[C:6](Cl)[CH:5]=1)([O-:3])=[O:2].[S-:12][C:13]1[CH:18]=[CH:17][CH:16]=CC=1.[Na+]>>[S:12]1[CH:16]=[CH:17][CH:18]=[C:13]1[C:7]1[CH:8]=[CH:9][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][C:6]=1[C:16]1[S:12][CH:13]=[CH:18][CH:17]=1

Participants

3

Reactant 2

HCID 74431,2-Dichloro-4-nitrobenzeneHCID 4110039Sodium benzenethiolate

Product 1

HCID 22765592HCID 22765592, compoundYield 31%

Procedure

The procedure was as previously mentioned using 1-nitro-3,4-dichlorobenzene (10 g, 0.052 M) and sodium thiophenoxide (13.75 g, 0.104 M). mp = 97°-101°. Yield 31%. The reaction product was characterized by NMR, 13CNMR, ir, and Mass Spectra (M+ = 339).

Sources & evidence

ORD record
ord-8f577ca5c6d446658eebac02006fdba0
Source dataset
uspto-grants-1978_10
Patent number
US04119629

Reaction notes

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