m-Chloroperbenzoic acid → 2-[(2-Fluorophenyl)methanesulfinyl]-1-oxo-1lambda~5~-pyridine

HRID 1112066Notes

Reaction equation

HRID 1112066 reaction equation
[F:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16].C1C=C(Cl)C=C(C(OO)=[O:25])C=1>C(Cl)(Cl)Cl>[F:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16])=[O:25]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 45692353HCID 45692353, compound

Product 1

HCID 540137552-[(2-Fluorophenyl)methanesulfinyl]-1-oxo-1lambda~5~-pyridine

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical to that of Example 68 using 5.7 gm (0.024 mol) 2-(2-fluorophenylmethylthio)pyridine N-oxide in 50 ml of chloroform with 4.8 gm (0.024 mol) MCPBA in 75 ml chloroform.

Sources & evidence

ORD record
ord-f2d1f4fc8b0b4802956803d99ca59565
Source dataset
uspto-grants-1978_10
Patent number
US04120692

Reaction notes

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