m-Chloroperbenzoic acid → 4-[(1-Oxo-1lambda~5~-pyridine-2-sulfinyl)methyl]benzonitrile

HRID 1112067Notes

Reaction equation

HRID 1112067 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([CH2:9][S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])=[CH:5][CH:4]=1)#[N:2].C1C=C(Cl)C=C(C(OO)=[O:26])C=1>C(Cl)(Cl)Cl>[C:1]([C:3]1[CH:8]=[CH:7][C:6]([CH2:9][S:10]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])=[O:26])=[CH:5][CH:4]=1)#[N:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 8605527HCID 8605527, compound

Product 1

HCID 544049394-[(1-Oxo-1lambda~5~-pyridine-2-sulfinyl)methyl]benzonitrile

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical to that of Example 68 using 3.6 gm (0.015 mol) 2-(4-cyanophenylmethylthio)pyridine N-oxide in 50 ml of chloroform with 3 gm (0.015 mol) MCPBA in 50 ml chloroform.

Sources & evidence

ORD record
ord-cc48745a33794e2eb4e1f7c67e4fec6f
Source dataset
uspto-grants-1978_10
Patent number
US04120692

Reaction notes

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