m-Chloroperbenzoic acid → Pyridine, 2-[[(3-methylphenyl)methyl]sulfinyl]-, 1-oxide

HRID 1112071Notes

Reaction equation

HRID 1112071 reaction equation
[CH3:1][C:2]1[CH:3]=[C:4]([CH2:8][S:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=2[O-:16])[CH:5]=[CH:6][CH:7]=1.C1C=C(Cl)C=C(C(OO)=[O:25])C=1>C(Cl)(Cl)Cl>[CH3:1][C:2]1[CH:3]=[C:4]([CH2:8][S:9]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=2[O-:16])=[O:25])[CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 47095513HCID 47095513, compound

Product 1

HCID 501070Pyridine, 2-[[(3-methylphenyl)methyl]sulfinyl]-, 1-oxide

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical with that of Example 68 using 4.6 gm (0.02 mol) 2-(3-Methylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform and 4 gm (0.02 mol) MCPBA in 100 ml chloroform.

Sources & evidence

ORD record
ord-4913f22a21294a919097591feeb62027
Source dataset
uspto-grants-1978_10
Patent number
US04120692

Reaction notes

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