m-Chloroperbenzoic acid → 2-[(3,4-Dichlorophenyl)methanesulfinyl]-1-oxo-1lambda~5~-pyridine

HRID 1112073Notes

Reaction equation

HRID 1112073 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH2:9][S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])[CH:5]=[CH:6][C:7]=1[Cl:8].C1C=C(Cl)C=C(C(OO)=[O:26])C=1>C(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:3]=[C:4]([CH2:9][S:10]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])=[O:26])[CH:5]=[CH:6][C:7]=1[Cl:8]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 47095501HCID 47095501, compound

Product 1

HCID 542767722-[(3,4-Dichlorophenyl)methanesulfinyl]-1-oxo-1lambda~5~-pyridine

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical to that of Example 68 using 8 gm (0.028 mol) B 2-(3,4-dichlorophenylmethylthio)pyridine N-oxide in 50 ml of chloroform and 5.6 gm (0.028 mol) MCPBA in 100 ml chloroform.

Sources & evidence

ORD record
ord-914a3d02226847248cb682cc3cdf1c56
Source dataset
uspto-grants-1978_10
Patent number
US04120692

Reaction notes

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