Diethylamine → HCID 21333309, compound

HRID 1112594Notes

Reaction equation

HRID 1112594 reaction equation
C(CO[C:5](=[O:31])[C:6]1[CH:11]=[CH:10][C:9]([C:12]([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:8][N:7]=1)#N.[CH2:32]([NH:34][CH2:35][CH3:36])[CH3:33]>O>[CH2:32]([N:34]([CH2:35][CH3:36])[C:5](=[O:31])[C:6]1[CH:11]=[CH:10][C:9]([C:12]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)([C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=2)[C:25]2[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=2)=[CH:8][N:7]=1)[CH3:33]

Participants

4

Reactant 2

HCID 8021DiethylamineHCID 21333313HCID 21333313, compound

Product 1

HCID 21333309HCID 21333309, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Heat at reflux for 6 hours a mixture of 0.1 mole of cyanomethyl-5-(triphenylmethyl)-picolinate and 0.5 moles of diethylamine. Cool the reaction mixture, pour into water and extract with chloroform. Dry the chloroform layer over anhydrous sodium sulfate and evaporate to obtain thereby the product of this example.

Workup

  1. temperatureHeat
  2. temperatureat reflux for 6 hours
  3. temperatureCool the reaction mixture
  4. extractionextract with chloroform
  5. dry with materialDry the chloroform layer over anhydrous sodium sulfate
  6. customevaporate
  7. customto obtain

Sources & evidence

ORD record
ord-2879bc455fe341d4a0ea96eebb9c6096
Source dataset
uspto-grants-1978_10
Patent number
US04123433

Reaction notes

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