Acetone → Dimethyl peroxide

HRID 1113153Notes

Reaction equation

HRID 1113153 reaction equation
[Br:5][c:6]1[cH:7][c:8]2[c:9]([cH:13][c:14]1[OH:15])[CH2:10][CH2:11][O:12]2.[CH3:1][O:2][O:3][CH3:4].[CH3:21][C:22](=[O:23])[CH3:24].[Cl:25][C:26](=[O:27])[O:28][CH2:29][CH3:30].[Li:16][CH2:17][CH2:18][CH2:19][CH3:20].[O:31]1[CH2:32][CH2:33][CH2:34][CH2:35]1>>[CH3:1][O:2][O:3][CH3:4].[c:6]1([C:26](=[O:27])[O:28][CH2:29][CH3:30])[cH:7][c:8]2[c:9]([cH:13][c:14]1[OH:15])[CH2:10][CH2:11][O:12]2

Participants

8

Reactant 6

HCID 180AcetoneHCID 8028TetrahydrofuranHCID 10928Ethyl chloroformateHCID 136492Dimethyl peroxideHCID 143976466-Bromo-2,3-dihydrobenzofuran-5-olHCID 178418339Butyllithium

Product 2

HCID 136492Dimethyl peroxideHCID 70373172Ethyl 5-hydroxy-2,3-dihydro-1-benzofuran-6-carboxylate

Sources & evidence

ORD record
ord-491fc03112304501814623f321091963
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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