Toluene → 1-(Azidomethyl)-3-methoxy-5-nitrobenzene

HRID 1123414Notes

Reaction equation

HRID 1123414 reaction equation
[CH3:29][O:30][c:31]1[cH:32][c:33]([CH2:40][OH:41])[cH:34][c:35]([N+:37](=[O:38])[O-:39])[cH:36]1.[CH3:42][c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1.[N:18]12[CH2:19][CH2:20][CH2:21][N:22]=[C:23]1[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28]2.[c:1]1([P:2]([c:3]2[cH:4][cH:5][cH:6][cH:7][cH:8]2)(=[O:9])[N:15]=[N+:16]=[N-:17])[cH:10][cH:11][cH:12][cH:13][cH:14]1>>[N:15](=[N+:16]=[N-:17])[CH2:40][c:33]1[cH:32][c:31]([O:30][CH3:29])[cH:36][c:35]([N+:37](=[O:38])[O-:39])[cH:34]1

Participants

5

Reactant 4

HCID 1140TolueneHCID 811841,8-Diazabicyclo(5.4.0)undec-7-eneHCID 199401P,P-Diphenylphosphinic azideHCID 45091344(3-Methoxy-5-nitrophenyl)methanol

Product 1

HCID 811549411-(Azidomethyl)-3-methoxy-5-nitrobenzene

Sources & evidence

ORD record
ord-8798ca2bc7964a819dca6a6507960081
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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