Acetate → Ethyl (3-{4-[(diphenylmethylene)amino]phenyl}cyclohexyl)acetate

HRID 1123723Notes

Reaction equation

HRID 1123723 reaction equation
[C:27](=[O:28])([O-:29])[O-:30].[C:79]([c:80]1[cH:81][cH:82][cH:83][cH:84][cH:85]1)([c:86]1[cH:87][cH:88][cH:89][cH:90][cH:91]1)=[NH:92].[CH2:93]1[O:94][CH2:95][CH2:96][CH2:97]1.[Cs+:31].[Cs+:32].[F:1][C:2]([F:3])([F:4])[S:5]([O:6][c:7]1[cH:8][cH:9][c:10]([CH:13]2[CH2:14][CH:15]([CH2:19][C:20](=[O:21])[O:22][CH2:23][CH3:24])[CH2:16][CH2:17][CH2:18]2)[cH:11][cH:12]1)(=[O:25])=[O:26].[O-:103][C:104]([CH3:105])=[O:106].[O-:99][C:100]([CH3:101])=[O:102].[Pd+2:98].[cH:33]1[cH:34][cH:35][c:36]([P:37]([c:38]2[cH:39][cH:40][c:41]3[c:42]([cH:43][cH:44][cH:45][cH:46]3)[c:47]2-[c:48]2[c:49]3[c:50]([cH:51][cH:52][cH:53][cH:54]3)[cH:55][cH:56][c:57]2[P:58]([c:59]2[cH:60][cH:61][cH:62][cH:63][cH:64]2)[c:65]2[cH:66][cH:67][cH:68][cH:69][cH:70]2)[c:71]2[cH:72][cH:73][cH:74][cH:75][cH:76]2)[cH:77][cH:78]1>>[c:7]1([N:92]=[C:79]([c:80]2[cH:81][cH:82][cH:83][cH:84][cH:85]2)[c:86]2[cH:87][cH:88][cH:89][cH:90][cH:91]2)[cH:8][cH:9][c:10]([CH:13]2[CH2:14][CH:15]([CH2:19][C:20](=[O:21])[O:22][CH2:23][CH3:24])[CH2:16][CH2:17][CH2:18]2)[cH:11][cH:12]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 8028TetrahydrofuranHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 136809Benzophenone imineHCID 634876Binap, (A+-)-HCID 59464250Ethyl [3-(4-{[(trifluoromethyl)sulphonyl]oxy}phenyl)cyclohexyl]acetate

Product 1

HCID 59464258Ethyl (3-{4-[(diphenylmethylene)amino]phenyl}cyclohexyl)acetate

Sources & evidence

ORD record
ord-41c6284a8a444af985bd8a79ca5dade9
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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