HRID1135192

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

2 次

HCID6344

Dichloromethane

CH2Cl2

HCID8471

Triethylamine

C6H15N

HCID27099

Copper(2+)

Cu+2

HCID11107815

4-(tert-Butyldimethylsilyloxy)phenylboronic acid

C12H21BO3Si

结构：CC(C)(C)OC(=O)N(CCc1ccc(O)cc1)CC(O)c1cccc(Cl)c1

HCID178453298

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)N(CCc1ccc(Oc2ccc(O[Si](C)(C)C(C)(C)C)cc2)cc1)CC(O)c1cccc(Cl)c1

HCID178453297

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-ca9c3ef5ff8043f6bc50787d98b00d86
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (7/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (7/10)

反应 SMILES

[C:28]([CH3:29])([CH3:30])([CH3:31])[Si:32]([O:33][c:34]1[cH:35][cH:36][c:37]([B:40]([OH:41])[OH:42])[cH:38][cH:39]1)([CH3:43])[CH3:44].[C:55]([O-:56])(=[O:57])[CH3:58].[C:60]([O-:61])(=[O:62])[CH3:63].[CH3:45][CH2:46][N:47]([CH2:48][CH3:49])[CH2:50][CH3:51].[Cl:1][c:2]1[cH:3][c:4]([CH:8]([CH2:9][N:10]([C:11]([O:12][C:13]([CH3:14])([CH3:15])[CH3:16])=[O:17])[CH2:18][CH2:19][c:20]2[cH:21][cH:22][c:23]([OH:26])[cH:24][cH:25]2)[OH:27])[cH:5][cH:6][cH:7]1.[Cl:52][CH2:53][Cl:54].[Cu+2:59]>>[Cl:1][c:2]1[cH:3][c:4]([CH:8]([CH2:9][N:10]([C:11]([O:12][C:13]([CH3:14])([CH3:15])[CH3:16])=[O:17])[CH2:18][CH2:19][c:20]2[cH:21][cH:22][c:23]([O:26][c:37]3[cH:36][cH:35][c:34]([O:33][Si:32]([C:28]([CH3:29])([CH3:30])[CH3:31])([CH3:43])[CH3:44])[cH:39][cH:38]3)[cH:24][cH:25]2)[OH:27])[cH:5][cH:6][cH:7]1