Dimethylformamide → HCID 178499359, compound

HRID 1142260Notes

Reaction equation

HRID 1142260 reaction equation
[C:59](=[O:60])([O-:61])[O-:62].[CH3:35][c:36]1[cH:37][cH:38][c:39]([S:40]([O:41][CH2:46][CH:47]2[N:48]([C:52](=[O:53])[O:54][C:55]([CH3:56])([CH3:57])[CH3:58])[CH2:49][CH2:50][CH2:51]2)(=[O:42])=[O:43])[cH:44][cH:45]1.[CH3:65][N:66]([CH3:67])[CH:68]=[O:69].[Cl:1][c:2]1[c:3]([CH:9]([CH3:10])[O:11][c:12]2[c:13]([C:31](=[O:32])[O:33][CH3:34])[s:14][c:15](-[n:17]3[cH:18][n:19][c:20]4[c:21]3[cH:22][c:23]([CH2:26][S:27](=[O:28])(=[O:29])[CH3:30])[cH:24][cH:25]4)[cH:16]2)[cH:4][cH:5][cH:6][c:7]1[OH:8].[Cs+:63].[Cs+:64]>>[Cl:1][c:2]1[c:3]([CH:9]([CH3:10])[O:11][c:12]2[c:13]([C:31](=[O:32])[O:33][CH3:34])[s:14][c:15](-[n:17]3[cH:18][n:19][c:20]4[c:21]3[cH:22][c:23]([CH2:26][S:27](=[O:28])(=[O:29])[CH3:30])[cH:24][cH:25]4)[cH:16]2)[cH:4][cH:5][cH:6][c:7]1[O:8][CH2:46][CH:47]1[N:48]([C:52](=[O:53])[O:54][C:55]([CH3:56])([CH3:57])[CH3:58])[CH2:49][CH2:50][CH2:51]1

Participants

6

Reactant 5

HCID 6228DimethylformamideHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 13110388tert-Butyl 2-((tosyloxy)methyl)pyrrolidine-1-carboxylateHCID 68574624HCID 68574624, compound

Product 1

HCID 178499359HCID 178499359, compound

Sources & evidence

ORD record
ord-275c4ac5c15a46a38964365205b185e6
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

Loading…