HRID1143356

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID962

Water

H2O

HCID8028

Tetrahydrofuran

C4H8O

HCID8058

n-Hexane

C6H14

HCID12679

Hexamethylphosphoramide

C6H18N3OP

HCID61124

beta-Homocyclocitral

C11H18O

HCID70536

p-((Trimethylsilyl)oxy)benzaldehyde

C10H14O2Si

结构：c1ccc([P+](CCC2OCCCO2)(c2ccccc2)c2ccccc2)cc1

HCID2724169

未命名化合物

HCID5460504

Phosphonium

H4P+

HCID178418339

未命名化合物

PRODUCTS

生成物

HCID54024878

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-0546c3e4daf8495d922cfdadfc75cdff
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (7/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (7/10)

反应 SMILES

[Br-:13].[CH2:42]([Li:43])[CH2:44][CH2:45][CH3:46].[CH2:60]1[O:61][CH2:62][CH2:63][CH2:64]1.[CH3:1][C:2]1=[C:3]([CH2:10][CH:11]=[O:12])[C:4]([CH3:8])([CH3:9])[CH2:5][CH2:6][CH2:7]1.[CH3:47][Si:48]([CH3:49])([CH3:50])[O:51][c:52]1[cH:53][cH:54][c:55]([CH:56]=[O:57])[cH:58][cH:59]1.[CH3:65][CH2:66][CH2:67][CH2:68][CH2:69][CH3:70].[CH3:72][N:73]([CH3:74])[P:75]([N:76]([CH3:77])[CH3:78])([N:79]([CH3:80])[CH3:81])=[O:82].[O:14]1[CH:15]([CH2:20][CH2:21][P+:22]([c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)([c:29]2[cH:30][cH:31][cH:32][cH:33][cH:34]2)[c:35]2[cH:36][cH:37][cH:38][cH:39][cH:40]2)[O:16][CH2:17][CH2:18][CH2:19]1.[OH2:71].[PH4+:41]>>[CH3:1][C:2]1=[C:3]([CH2:10][CH:11]=[CH:21][CH2:20][CH:15]2[O:14][CH2:19][CH2:18][CH2:17][O:16]2)[C:4]([CH3:8])([CH3:9])[CH2:5][CH2:6][CH2:7]1