Selenium Dioxide → 3-Chloro-6'-formyl-[2,3]bipyridyl-5-carboxylic acid methyl ester

HRID 1146297Notes

Reaction equation

HRID 1146297 reaction equation
[CH2:22]1[O:23][CH2:24][CH2:25][O:26][CH2:27]1.[CH3:1][O:2][C:3](=[O:4])[c:5]1[cH:6][c:7]([Cl:18])[c:8](-[c:11]2[cH:12][n:13][c:14]([CH3:17])[cH:15][cH:16]2)[n:9][cH:10]1.[Se:19](=[O:20])=[O:21]>>[CH3:1][O:2][C:3](=[O:4])[c:5]1[cH:6][c:7]([Cl:18])[c:8](-[c:11]2[cH:12][n:13][c:14]([CH:17]=[O:20])[cH:15][cH:16]2)[n:9][cH:10]1

Participants

4

Reactant 3

HCID 24007Selenium DioxideHCID 312751,4-DioxaneHCID 57825687Methyl 3-chloro-6'-methyl[2,3'-bipyridine]-5-carboxylate

Product 1

HCID 578256963-Chloro-6'-formyl-[2,3]bipyridyl-5-carboxylic acid methyl ester

Sources & evidence

ORD record
ord-789ae76a437742bf9558e890cbc16087
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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