1,2-Dichloroethane → Tert-butyl 2-benzamido-3-oxobutanoate

HRID 1148483Notes

Reaction equation

HRID 1148483 reaction equation
[C:27]([O-:28])(=[O:29])[CH3:30].[C:31]([O-:32])(=[O:33])[CH3:34].[C:35]([O-:36])(=[O:37])[CH3:38].[C:39]([O-:40])(=[O:41])[CH3:42].[Cl:23][CH2:24][CH2:25][Cl:26].[N+:1](=[N-:2])=[C:3]([C:4](=[O:5])[O:6][C:7]([CH3:8])([CH3:9])[CH3:10])[C:11]([CH3:12])=[O:13].[NH2:14][C:15](=[O:16])[c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1.[Rh+3:43].[Rh+3:44]>>[NH:1]([CH:3]([C:4](=[O:5])[O:6][C:7]([CH3:8])([CH3:9])[CH3:10])[C:11]([CH3:12])=[O:13])[C:15](=[O:16])[c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1

Participants

6

Reactant 5

HCID 111,2-DichloroethaneHCID 175Acetate4×HCID 2331BenzamideHCID 167511Rhodium(3+)2×HCID 538143121-tert-Butoxy-2-diazonio-3-oxobut-1-en-1-olate

Product 1

HCID 58551885Tert-butyl 2-benzamido-3-oxobutanoate

Sources & evidence

ORD record
ord-a76563161f23419da4d168c0e2834afd
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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