Toluene → Bromide ion

HRID 1150490Notes

Reaction equation

HRID 1150490 reaction equation
[Br:1][CH2:2][c:3]1[cH:4][c:5]([O:13][S:14](=[O:15])(=[O:16])[C:17]([F:18])([F:19])[F:20])[c:6]([C:7](=[O:8])[O:9][CH3:10])[cH:11][cH:12]1.[CH3:40][c:41]1[cH:42][cH:43][cH:44][cH:45][cH:46]1.[c:21]1([P:27]([c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[cH:22][cH:23][cH:24][cH:25][cH:26]1>>[Br-:1].[CH2:2]([c:3]1[cH:4][c:5]([O:13][S:14](=[O:15])(=[O:16])[C:17]([F:18])([F:19])[F:20])[c:6]([C:7](=[O:8])[O:9][CH3:10])[cH:11][cH:12]1)[P+:27]([c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1)([c:28]1[cH:29][cH:30][cH:31][cH:32][cH:33]1)[c:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1

Participants

5

Reactant 3

HCID 1140TolueneHCID 11776TriphenylphosphineHCID 18474595Methyl 4-bromomethyl-2-trifluoromethylsulfonyloxybenzoate

Product 2

HCID 259Bromide ionHCID 86758316[4-Methoxycarbonyl-3-(trifluoromethylsulfonyloxy)phenyl]methyl-triphenylphosphanium

Sources & evidence

ORD record
ord-8d20cf8c5a7a41da88f8328379470ccd
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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