1,2-Dimethoxyethane → 2-Bromo-6-[7,7-dimethyl-1-oxo-3,4,7,8-tetrahydro-1H-cyclopenta[4,5]pyrrolo[1,2-a]pyrazin-2(6H)-yl]benzyl Acetate

HRID 1151473Notes

Reaction equation

HRID 1151473 reaction equation
[C:16]([CH3:17])(=[O:18])[O:19][CH2:20][c:21]1[c:22]([Br:28])[cH:23][cH:24][cH:25][c:26]1[Br:27].[CH3:1][C:2]1([CH3:15])[CH2:3][c:4]2[n:5]3[c:10]([cH:11][c:12]2[CH2:13]1)[C:9](=[O:14])[NH:8][CH2:7][CH2:6]3.[CH3:31][O:32][CH2:33][CH2:34][O:35][CH3:36].[Cu:29][I:30]>>[CH3:1][C:2]1([CH3:15])[CH2:3][c:4]2[n:5]3[c:10]([cH:11][c:12]2[CH2:13]1)[C:9](=[O:14])[N:8]([c:22]1[c:21]([CH2:20][O:19][C:16]([CH3:17])=[O:18])[c:26]([Br:27])[cH:25][cH:24][cH:23]1)[CH2:7][CH2:6]3

Participants

5

Reactant 4

HCID 80711,2-DimethoxyethaneHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 580442027,7-dimethyl-3,4,7,8-tetrahydro-2H-cyclopenta[4,5]pyrrolo[1,2-a]pyrazin-1(6H)-oneHCID 592164132,6-Dibromobenzyl acetate

Product 1

HCID 680968852-Bromo-6-[7,7-dimethyl-1-oxo-3,4,7,8-tetrahydro-1H-cyclopenta[4,5]pyrrolo[1,2-a]pyrazin-2(6H)-yl]benzyl Acetate

Sources & evidence

ORD record
ord-fa1032cca06d4a209bbc3bc70d725e35
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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