Bromide ion → 8-(2-Chlorophenylmethylene)-1,4-dioxaspiro[4.5]decane

HRID 1152553Notes

Reaction equation

HRID 1152553 reaction equation
[Br-:1].[CH2:29]([Li:30])[CH2:31][CH2:32][CH3:33].[CH2:34]1[CH2:35][O:36][C:37]2([CH2:38][CH2:39][C:40](=[O:43])[CH2:41][CH2:42]2)[O:44]1.[Cl:2][c:3]1[c:4]([CH2:9][P+:10]([c:11]2[cH:12][cH:13][cH:14][cH:15][cH:16]2)([c:17]2[cH:18][cH:19][cH:20][cH:21][cH:22]2)[c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)[cH:5][cH:6][cH:7][cH:8]1.[O:45]1[CH2:46][CH2:47][CH2:48][CH2:49]1>>[Cl:2][c:3]1[c:4]([CH:9]=[C:40]2[CH2:39][CH2:38][C:37]3([O:36][CH2:35][CH2:34][O:44]3)[CH2:42][CH2:41]2)[cH:5][cH:6][cH:7][cH:8]1

Participants

6

Reactant 5

HCID 259Bromide ionHCID 8028TetrahydrofuranHCID 494175(2-Chlorobenzyl)(triphenyl)phosphoraneHCID 5674151,4-Dioxaspiro[4.5]decan-8-oneHCID 178418339Butyllithium

Product 1

HCID 197052048-(2-Chlorophenylmethylene)-1,4-dioxaspiro[4.5]decane

Sources & evidence

ORD record
ord-377c0055de9c497e96cbdb7e3e68f5af
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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