Benzyl Bromide → HCID 20563345, compound

HRID 1154776Notes

Reaction equation

[CH2:1]=[C:2]1[C:15](=[CH2:16])[CH:14]2[O:17][CH:3]1[C:4]1[CH2:5][C:6]3[CH:7]=[CH:8][CH:9]=[C:10]([OH:18])[C:11]=3[CH2:12][C:13]=12.[CH2:19](Br)[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>>[CH2:19]([O:18][C:10]1[CH:9]=[CH:8][CH:7]=[C:6]2[C:11]=1[CH2:12][C:13]1[CH:14]3[O:17][CH:3]([C:4]=1[CH2:5]2)[C:2](=[CH2:1])[C:15]3=[CH2:16])[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1

Participants

Reactant 2

HCID 7498Benzyl Bromide

HCID 20563350HCID 20563350, compound

Product 1

HCID 20563345HCID 20563345, compound

Procedure

By reacting the 1,2,3,4,9,10-hexahydro-2,3-dimethylene-1,4-epoxyanthracen-5-ol with benzyl bromide in place of methyl iodide in an analogous manner, there was obtained in good yield 1,2,3,4,9,10-hexahydro-5-benzyloxy-2,3-dimethylene-1,4-epoxyanthracene.

Workup

customthere was obtained

Sources & evidence

ORD record: ord-82d0b16dc26946bbad8722ef129c4824
Source dataset: uspto-grants-1981_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04298535

Reaction notes

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