Triethylamine → Methylthiomethyl Geranate

HRID 1155730Notes

Reaction equation

HRID 1155730 reaction equation
[C:1]([OH:12])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:10])[CH3:9])\[CH3:4].[CH3:13][S:14][CH2:15]Cl.C(N(CC)CC)C>>[C:1]([O:12][CH2:13][S:14][CH3:15])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:9])[CH3:10])\[CH3:4]

Participants

4

Reactant 3

HCID 8471TriethylamineHCID 16916Chloromethyl methyl sulfideHCID 5275520Geranic acid

Product 1

HCID 86738396Methylthiomethyl Geranate

Procedure

This product was prepared according to the procedure described in Example 1, by reacting geranic acid with chloromethyl methyl sulfide in the presence of one equivalent of triethylamine; b.p. 111°-112° C./2 mm Hg, n20 1.4912.

Workup

  1. customThis product was prepared

Sources & evidence

ORD record
ord-66067993e62146ceba9ba1e86f7129de
Source dataset
uspto-grants-1982_06
Patent number
US04332829

Reaction notes

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