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HRID1156191

反应详情

EQUATION

反应方程式

HRID 1156191 的结构方程式

REACTANTS

反应物

2
结构：C[Si](C)(C)C#CCBr
HCID642589

3-Bromo-1-(trimethylsilyl)-1-propyne

C6H11BrSi

结构：CCOC(=O)COc1cc2c(c(Cl)c1Cl)C(=O)C(c1ccc(Cl)cc1)C2
HCID12774097

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)COc1cc2c(c(Cl)c1Cl)C(=O)C(CC#C[Si](C)(C)C)(c1ccc(Cl)cc1)C2
HCID12774093

未命名化合物

PROCEDURE

实验过程

Reaction of ethyl [6,7-dichloro-1-oxo-2-(p-chlorophenyl)-5-indanyloxy]acetate with 1-bromo-3-(trimethylsilyl)-2-propyne according to the procedure of Example 1, STEP (b), affords the title compound, m.p. 103°-103.5°; purified by chromatography (silica-gel column eluted with chloroform-n-hexane) and crystallization from ether-cyclohexane.