Carbon Tetrachloride → 2-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL PHENYL SULFIDE

HRID 1156373Notes

Reaction equation

HRID 1156373 reaction equation
[CH:1]([S:3]([C:6]1[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][CH:7]=1)(=[O:5])=[O:4])=[CH2:2].[C:13]1([S:19]Cl)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.C(Cl)(Cl)(Cl)[Cl:22]>>[C:13]1([S:19][CH:1]([S:3]([C:6]2[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][CH:7]=2)(=[O:4])=[O:5])[CH2:2][Cl:22])[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1

Participants

4

Reactant 3

HCID 5943Carbon TetrachlorideHCID 217031-Chloro-4-(ethenylsulfonyl)benzeneHCID 11008040Benzenesulfenyl chloride

Product 1

HCID 130447952-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL PHENYL SULFIDE

Procedure

A solution of 29.4 g (0.145 mole) of p-chlorophenyl vinyl sulfone in 50 ml of carbon tetrachloride at 22° was treated with 21.0 g (0.145 mole) of benzenesulfenyl chloride. There was an exotherm to 32°. The solution was removed at reduced pressure and the residue recrystallized from benzene to give product of m.p. 108.5°-109.5° C.

Workup

  1. customto 32°
  2. customThe solution was removed at reduced pressure
  3. customthe residue recrystallized from benzene
  4. customto give product of m.p. 108.5°-109.5° C.

Sources & evidence

ORD record
ord-528b65ed9c3748fea057a06f50a274a6
Source dataset
uspto-grants-1982_06
Patent number
US04335142

Reaction notes

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