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HRID1157085

反应详情

EQUATION

反应方程式

HRID 1157085 的结构方程式

REACTANTS

反应物

2
结构：C#CCn1ccnc1[N+](=O)[O-]
HCID54675143

未命名化合物

结构：CC(=O)OC(CN=[N+]=[N-])COS(=O)(=O)c1ccc(C)cc1
HCID57540208

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)OC(COS(=O)(=O)c1ccc(C)cc1)Cn1cc(Cn2ccnc2[N+](=O)[O-])nn1
HCID59511047

未命名化合物

PROCEDURE

实验过程

2-Nitro-1-(prop-2-ynyl)-1H-imidazole 10 (0.2 g, 1.32 mmol) is heated with 1-azido-3-(tosyloxy)propan-2-yl acetate 15 (0.41 g, 1.32 mmol) at 60° C. overnight. The residue is purified by chromatography on silica gel (MeOH/CH2Cl2, 1:10) to afford 16.

WORKUP

后处理

  1. customThe residue is purified by chromatography on silica gel (MeOH/CH2Cl2, 1:10)