Azobisisobutyronitrile → HCID 20513502, compound

HRID 1164011Notes

Reaction equation

HRID 1164011 reaction equation
[CH3:1][O:2][C:3]1[C:8]([CH3:9])=[CH:7][CH:6]=[CH:5][C:4]=1[O:10][C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([Cl:17])[CH:12]=1.[Br:18]N1C(=O)CCC1=O.N(C(C)(C)C#N)=NC(C)(C)C#N>C1C=CC=CC=1>[CH3:1][O:2][C:3]1[C:8]([CH2:9][Br:18])=[CH:7][CH:6]=[CH:5][C:4]=1[O:10][C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([Cl:17])[CH:12]=1

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 67184N-bromobutanimideHCID 20513489HCID 20513489, compound

Product 1

HCID 20513502HCID 20513502, compoundYield 104%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A mixture of 3-chlorophenyl 2-methoxy-3-methylphenyl ether (14.6 g), N-bromosuccinimide (11.3 g) and 2,2'-azobisisobutyronitrile (1.1 g) in benzene (100 ml) was treated in a similar manner to that of Example 6-(3) to give oily 3-chlorophenyl 2-methoxy-3-bromomethylphenyl ether (20 g).

Workup

  1. additionwas treated in a similar manner to that of Example 6-(3)

Sources & evidence

ORD record
ord-474e9f11159842c6ac724d036542b202
Source dataset
uspto-grants-1983_01
Patent number
US04367238

Reaction notes

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