Acetic Acid → HCID 13066662, compound

HRID 1164018Notes

Reaction equation

HRID 1164018 reaction equation
O=[O+][O-].[CH3:4][O:5][C:6]1[C:11]([CH:12]=CC)=[CH:10][CH:9]=[CH:8][C:7]=1[O:15][C:16]1[C:17]([CH3:22])=[CH:18][CH:19]=[CH:20][CH:21]=1.C(O)(=[O:25])C>C(OCC)(=O)C>[CH3:4][O:5][C:6]1[C:7]([O:15][C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=2[CH3:22])=[CH:8][CH:9]=[CH:10][C:11]=1[CH:12]=[O:25]

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 24823OzoneHCID 70520034HCID 70520034, compound

Product 1

HCID 13066662HCID 13066662, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

Ozone gas was introduced to a solution of o-tolyl 2-methoxy-3-(1-propenyl)phenyl ether (30 g) in a mixture of ethyl acetate (200 ml) and glacial acetic acid (10 ml) with stirring under cooling for an hour. The reaction mixture was treated in a similar manner to that of Example 4-(3) to give oily 2-methoxy-3-(o-tolyloxy)benzaldehyde (28 g)

Workup

  1. temperatureunder cooling for an hour
  2. additionThe reaction mixture was treated in a similar manner to that of Example 4-(3)

Sources & evidence

ORD record
ord-58025fefcf7d483a8f3edd434440a95b
Source dataset
uspto-grants-1983_01
Patent number
US04367238

Reaction notes

Loading…