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HRID1164691

反应详情

EQUATION

反应方程式

HRID 1164691 的结构方程式

REACTANTS

反应物

2
结构：COc1ccc([Te](=O)c2ccc(OC)cc2)cc1
HCID3044917

Benzene, 1,1'-tellurinylbis(4-methoxy-

C14H14O3Te

结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C.O=C([O-])C1=CC=CC(=S)C1=S
HCID86738765

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](S)CC[C@]4(C)[C@H]3CC[C@]12C.O=C([O-])c1ccccc1
HCID86738764

未命名化合物

收率 70%

PROCEDURE

实验过程

5-Cholesten-3β-ol-dithionobenzoate (130 mg, 0.25 mmol) was reacted with bis-(p-methoxyphenyl)-telluroxide for 27 h. 5-Cholesten-3β-thiol-benzoate (88 mg, 70%), m.p. 160°-162° was obtained after p.l.c. (petroleum ether-ethyl acetate 20:1). The product obtained was recrystallised from ethyl acetate (65 mg, 52%), m.p. 164.5-166 (lit., 167°), νmax. (CCl4) 2800,2750,1670,1550,1250,1210,1180,920,865,810-740 (broad) and 700 cm-1, m/e 506 (M+ weak), 369, and 368 (100%).