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HRID1164693

反应详情

EQUATION

反应方程式

HRID 1164693 的结构方程式

REACTANTS

反应物

2
结构：COc1ccc([Te](=O)c2ccc(OC)cc2)cc1
HCID3044917

Benzene, 1,1'-tellurinylbis(4-methoxy-

C14H14O3Te

结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC[C@H]4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C.[O-]C(=[Se])c1ccccc1
HCID178443927

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC[C@H]4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C.O=C([O-])c1ccccc1
HCID86738769

未命名化合物

收率 93%

PROCEDURE

实验过程

5α-Cholestan-3β-ol-selenobenzoate (278 mg, 0.50 mmol) was reacted with bis-(p-methoxyphenyl)-telluroxide for 0.3 h. 5α-Cholestan-3β-ol-benzoate (229 mg, 93%) was obtained after p.l.c. (petroleum ether-ethyl acetate 9:1). The product obtained was recrystallized from ethyl acetate (198 mg, 80%) m.p. 136°-137° (lit., 136°-137°).