HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → HCID 19757849, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | Diethyl pyridin-3-ylphosphonate | HCID 10867660 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 19757849 | HCID 19757849 | — |
Reaction Steps
A solution of 1.5 g of 3-diethylphosphonopyridine, Bull. Chem. Soc. Jap. 55, 909 (1982), in 20 ml of methylene chloride is treated with 2.33 g m-chloroperbenzoic acid at room temperature. The reaction mixture is allowed to stir at room temperature overnight, then concentrated under vacuum. The residue is partitioned between ether and water, the aqueous layer is concentrated under vacuum to afford 3-(diethylphosphono)-pyridine-N-oxide as a yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04906621 |
| Source dataset | uspto-grants-1990_03 |
| ORD ID | ord-fef240fb309c4c0fb2ba15c4b0325317 |
| Source note | uspto-grants-1990_03 |