Benzyl Chloride → HCID 73655906, compound

HRID 1165087Notes

Reaction equation

HRID 1165087 reaction equation
[CH2:1]([O:4][N:5]=[C:6]([CH3:10])[CH2:7][CH2:8][OH:9])[CH:2]=[CH2:3].[CH2:11](Cl)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.C1COCC1.[OH-].[Na+]>>[CH2:11]([O:9][CH2:8][CH2:7][C:6](=[N:5][O:4][CH2:1][CH:2]=[CH2:3])[CH3:10])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

Participants

5

Reactant 4

HCID 7503Benzyl ChlorideHCID 8028TetrahydrofuranHCID 14798Sodium HydroxideHCID 54431952HCID 54431952, compound

Product 1

HCID 73655906HCID 73655906, compound

Conditions

Temperature
0 °C

Procedure

A reactor was charged with 0.1 mole of 3-allyloxyiminobutanol, 0.12 mole of benzyl chloride and 2 moles of THF. The mixture was cooled to 0° C., and 0.11 mole of sodium hydroxide was added little by little. The temperature of the mixture was returned to room temperature, and it was stirred for 2 hours. After the reaction, the product was isolated in a customary manner to give 3-allyloxyiminobutyl benzyl ether in a yield of 95 mole %.

Workup

  1. customwas returned to room temperature
  2. customAfter the reaction
  3. customthe product was isolated in a customary manner

Sources & evidence

ORD record
ord-9284801a03ff4766b8d37bbe517377f0
Source dataset
uspto-grants-1990_03
Patent number
US04906768

Reaction notes

Loading…