Methyl Ethyl Ketone → HCID 14748264, compound

HRID 1165250Notes

Reaction equation

HRID 1165250 reaction equation
[CH2:1]([C:6]1[CH:11]=[CH:10][C:9]([OH:12])=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH2:4][CH3:5].C(=O)([O-])[O-].[K+].[K+].[CH2:19]([C:21]([CH3:23])=[O:22])C>>[CH2:1]([C:6]1[CH:7]=[CH:8][C:9]([O:12][CH2:19][CH:21]2[CH2:23][O:22]2)=[CH:10][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH3:5]

Participants

4

Reactant 3

HCID 6569Methyl Ethyl KetoneHCID 11430Potassium CarbonateHCID 269754-Pentylphenol

Product 1

HCID 14748264HCID 14748264, compound

Procedure

A mixture of 44 g of 4-pentylphenol (Eastman Kodak), 50 ml of epichlolorohydrin, 120 g of potassium carbonate in 250 ml methyl ethyl ketone was refluxed for 12 hr. Residual after removal of solid and solvent was distilled through a Kugelrohr adaptor to give the title compound, bp 180°-195°/0.3 mmHg.

Workup

  1. temperaturewas refluxed for 12 hr
  2. customResidual after removal of solid and solvent
  3. distillationwas distilled through a Kugelrohr adaptor

Sources & evidence

ORD record
ord-2e775273336146dfac793334cab5687b
Source dataset
uspto-grants-1990_03
Patent number
US04908384

Reaction notes

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