Ammonia → HCID 15084956, compound

HRID 1165349Notes

Reaction equation

HRID 1165349 reaction equation
[NH3:1].CN.[Cl:4][C:5]1([Cl:14])[CH2:10][CH2:9][CH2:8][C:7]([Cl:12])([Cl:11])[C:6]1=O>[Ti](Cl)(Cl)(Cl)Cl.C1(C)C=CC=CC=1>[Cl:4][C:5]1([Cl:14])[CH2:10][CH2:9][CH2:8][C:7]([Cl:12])([Cl:11])[C:6]1=[NH:1]

Participants

6

Reactant 3

HCID 222AmmoniaHCID 6329MethylamineHCID 774072,2,6,6-Tetrachlorocyclohexan-1-one

Product 1

HCID 15084956HCID 15084956, compound

Reagents, catalysts & solvents 2

HCID 24193Titanium TetrachlorideCatalystHCID 1140TolueneSolvent

Procedure

The procedure of Example 1 was repeated except that 1.56 moles of each amine and ammonia shown in Table 1 was used instead of aniline to give oily 2,2,6,6-tetrachlorocyclohexaneimine derivative. In Examples 4 and 5, gaseous ammonia and methylamine were introduced into the mixture of 2,2,6,6-tetrachlorocyclohexanone, toluene and titanium tetrachloride, respectively. The structural formulae, yields and results of IR analysis of the obtained 2,2,6,6-tetrachlorocyclohexaneimine derivatives (I) are shown in Table 1.

Workup

  1. customThe structural formulae, yields

Sources & evidence

ORD record
ord-c5bfa53b59114b7da4868d125041d6b0
Source dataset
uspto-grants-1990_03
Patent number
US04908479

Reaction notes

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