Benzyl Chloride → HCID 21946369, compound

HRID 1165418Notes

Reaction equation

HRID 1165418 reaction equation
[SiH4].[NH2:2][CH2:3][CH2:4][NH:5][CH2:6][CH2:7][CH2:8][Si:9]([O:14][CH3:15])([O:12][CH3:13])[O:10][CH3:11].[CH2:16]([Cl:23])[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>[Cu]>[ClH:23].[CH2:16]([N:5]([CH2:4][CH2:3][NH2:2])[CH2:6][CH2:7][CH2:8][Si:9]([O:14][CH3:15])([O:10][CH3:11])[O:12][CH3:13])[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

Participants

5

Reactant 3

HCID 7503Benzyl ChlorideHCID 15659(Trimethoxysilylpropyl)ethylenediamineHCID 23953Silane

Product 1

HCID 21946369HCID 21946369, compound

Reagents, catalysts & solvents 1

HCID 23978CopperCatalyst

Procedure

Example 1 was repeated except that the copper foil was pretreated with a silane solution prepared as follows. 8.8 g. of N-2-amino-ethyl-3-aminopropyltrimethoxysilane (a product of Petrarch Systems, Inc.) and 5.0 g. of benzyl chloride were charged in a reaction vessel to produce 3-(N-Benzyl-2-aminoethylamino)-propyltrimethoxysilane hydrochloride. A 1% solution of this silane in methanol was prepared, the copper foil dipped therein for 30 minutes followed by air drying and a 5-minute bake at 105° C. The copper foil was laminated to similar prepregs (2-ply, 6.12 g, 59.8% polymer uptake) as described in Example 1 and cured at 180° to 220° C. for 30 minutes under psi pressure. A 2-ply 3"×6" laminate was obtained.

Workup

  1. customprepared

Sources & evidence

ORD record
ord-2183d4601fa849abbd7dad71fa059db2
Source dataset
uspto-grants-1990_03
Patent number
US04910077

Reaction notes

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